Joining: Light-Curable Adhesives
by Virginia P. Read
January 22, 2010
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| Adhesives with red or blue fluorescing
technology are used to bond polycarbonate substrates for easy in-line
inspection. |
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Manufacturers have recently faced the most challenging
economic conditions in decades and have aggressively sought means to reduce
costs without sacrificing product quality. Optimizing assembly process
efficiency and minimizing material consumption are viable pathways to
significant reductions in assembly manufacturing expense. Many assembly
operations are ideal for using adhesives for bonding and joining. In these
applications, light-curable materials (LCMs) offer several avenues to increase
productivity and reduce waste over traditional two-part slow-cure adhesives,
thermally-cured adhesives, or solvent-based adhesive systems.
Selecting the right adhesive to meet the performance,
production, and environmental demands of an appliance assembly application can
be a daunting decision process. Many factors must be considered before choosing
a method to bond and seal plastic, metal, glass, or other substrates. Yet,
despite a multitude of available options, the decision-making process can be
simplified by knowing the right questions to ask.
Establishing the application requirements for the adhesive
or sealant and identifying the ideal performance criteria provide the
foundation for the selection process. The major requirements and ideal
performance criteria for adhesives and sealants used in the bonding of plastic,
glass, metal, or other substrates to similar or dissimilar materials are listed
in Table 1.
Vigorous global competition, coupled with environmental
mandates, compel manufacturers to consider far more than just the lowest
price-per-gram in selecting an adhesive. Light-curable systems frequently
provide the highest product quality and the most cost-efficient process with
the least environmental impact, in comparison to slow-cure adhesives, and sonic
and solvent-welding processes. Table 2 shows a comparison of the benefits and
limitations of various plastic joining technologies.
Light-curable adhesive systems can enable numerous assembly
process improvements in the areas of throughput, quality, durability, labor
costs, and improved work safety.
Material cost savings can also be achieved with
light-curable adhesives. Consider a two-component, urethane adhesive which has
a dollar per lb. material price less than that of a one-component,
light-curable acrylic. The expected material cost benefit of the lower-priced,
two-part system vanishes in a side-by-side study which reveals higher two-part
material usage due to purging, improper mixing, and general waste in the mixing
system.
Selection considerations
Selecting the best adhesive for a specific
appliance assembly operation should consider several important factors.
Chemistry
When bonding engineered plastics such as polycarbonate, acrylic, urethane, ABS, nylon, or other resin systems to other plastics, metal, or glass, there are several adhesive chemistry options. These include light-curable acrylated urethanes, cyanoacrylates, one-part or two-part urethanes, and even a few hybrid combination adhesives such as thermally-curable and light-curable adhesives or light-curable silicone hybrid systems. Bonding to silicones is often best accomplished with silicone adhesives, but under the right conditions bonding to silicone elastomers can be done with urethanes.
Viscosity and thixotropy
Viscosity is the measure of a fluid’s resistance to flow. The lower a fluid’s viscosity, the greater the fluid’s ability or tendency to flow or spread over a surface or bond joint. As a point of reference in evaluating viscosity of an adhesive, water has a viscosity of 1 cP and honey has a viscosity of 10,000 cP. Potting or filling a groove molded into plastic would likely require a low-to-medium viscosity fluid, as a low viscosity material will self-level and fill the groove without voids or air bubbles.
An additional property for consideration is thixotropy. Materials which are thixotropic flow easily when placed under shear (e.g., during dispensing), but exhibit a higher viscosity when the shear force is removed (dispensing stops). For example, ketchup, which has viscosity around 10,000 cP and is thixotropic, flows easily when dispensed, but stays in-place on top of the hot dog. The thixotropic index (recovery) of a material is a helpful value. Typically materials with values of 2.0 to 3.5 are very thick or gel-like and materials with values of 1.5 to 2.0 tend to slump. A thixotropic material would be an ideal candidate to create a gasket bead profile on an unrestricted, open surface. This bead (which will act as a moisture, sound, or chemical barrier) must be easily dispensed and maintain its profile prior to cure without the assistance of the assembly structure.
Adhesion
Once the adhesive chemistry is selected, an individual product within that adhesive class should be chosen based upon its adhesion to various substrates. The test criteria are defined by the specific performance expectations of the adhesive, based on the design of the components. Lap-shear testing or peel-force testing is common, as well as pressurization to burst or leak testing. Accelerated aging tests criteria will depend on the expected storage and in-use conditions expected over the life of the device. Attempting to “accelerate the accelerated aging test” by employing even more aggressive conditions should be avoided. Conducting the test at too high a temperature may inaccurately characterize the adhesive by creating additional cross-linking within the adhesive, which in turn will cause a reduction in elongation properties.
Ease of processing
If multiple adhesive choices still remain,
evaluate the adhesive based on its ease of processing. One-part adhesives
require a simple dispensing system versus a metered mix system for two-part
adhesives. Additionally, one-part systems usually do not require dispensing
system purging or have issues with pot life. The ability to dispense and cure
where and when needed make one-part acrylated urethanes ideal for many
appliance assembly applications, requiring only that light (UV or visible)
reach some portion of the bond line. A careful consideration of the level of
automation required for the assembly operation (manual, semi-automated, or
fully automated) is also important. Can the system be stopped or shut off
easily, or is there a shut down that needs to be followed? Can the process be
adjusted or qualified to handle lot-to-lot variation in viscosity or cure time?
Quality enhancement
Since the quality and reliability of the appliance product is of the utmost importance, the ability to assure a high-quality adhesive bond is critical. Some appliance assembly adhesives are formulated to fluoresce under a black light. This enables quality technicians to confirm that the adhesive covers the prescribed bond or seal area, and also to detect any leaks, air bubbles, or voids. Fluorescing adhesive formulations are available in both blue and red fluorescing color versions. Red is particularly useful in providing the proper contrast in situations where the surrounding plastics also fluoresce blue. An innovative, recent advancement that even further assures joint quality is the introduction of See-Cure technology. This technology offers a blue color in the uncured adhesive which changes to clear/colorless once cure has been completed. A simple, post-cure visual inspection can thus determine completeness of adhesive cure.
Cost
The true in-use cost of an adhesive considers all aspects of
the process including waste, downtime, start-up time, scheduled maintenance,
tight quality specifications to minimize variability within the process, the
number of workers required for a specific process, and scrap rate. Two
adhesives may differ only slightly in their price per gram, yet one of these
materials may deliver at least a 30 percent cost savings in process
efficiencies.
Savings opportunities
Cost savings in the assembly operation drop
directly to the company’s bottom line. These can be achieved in several areas.
Materials
High-performance adhesives often cost more than
commodity materials such as two-part epoxies, thermally-cured adhesives,
solvent-based adhesives, or one-part moisture cure silicones. Since
light-curable materials are one-part formulations, there is less material waste
than two-part systems. With one-part chemistry adhesives, it is not necessary
to purge the dispense system and dispose of the dispense tips or static mixing
tips because of an incorrect mix ratio.
Assembly labor
Light-curable materials reduce labor costs by
eliminating the costs associated with stacking and racking parts of slow-curing
adhesives. Light-curable materials cure on-demand, ensuring that the bonded
appliance assembly is immediately ready for the next step in the process.
Assembly labor costs can be reduced by up to 70 percent over two-part epoxy
systems, two-part silicone systems, or one-part silicone systems. Consider
parts on racks awaiting their turn in a cure oven, cooling after the cure oven,
or drying on racks for three to seven days. The labor associated with racking,
and loading into cure ovens is eliminated with the use of light-curable
materials. Unlike other adhesive products, there is no need to be concerned
with environmental conditions such as high humidity adversely impacting the
adhesive chemistry system.
QA testing
On-demand cure enables QA check of the bond-line immediately
following the cure, thus eliminating the retrieval of defective parts. This
immediate check minimizes scrap and work-in-process. The fluorescing of some
adhesives allows for void or bubble detection. Manufacturers can then fix and
repair, or scrap these parts before adding additional value to the part through
down-stream operations. On a high-speed
assembly production line, for instance, a high-speed camera can detect and
confirm the post-cure presence of adhesive on the bond-line via the fluorescing
of the adhesive under black light. Red fluorescing is particularly useful in
providing the proper contrast in situations where the surrounding plastics also
fluoresce blue. An innovative, recent advancement that even further assures
joint quality is the introduction of See-Cure technology. A simple, post-cure
visual inspection can thus determine completeness of adhesive cure.
Light-curable materials can reduce QA testing costs up to 50 percent over
traditional adhesive chemistries.
Inventory
The inventory costs associated with assembly processes
utilizing light-curable materials can be reduced by up to 50 percent over
traditional adhesive chemistries. These reductions in inventory costs result
from on-demand cure and instant QC testing which eliminates excess inventory of
slow-curing commodity adhesives. Light-curable adhesive systems avoid costly
waste due to improper mixing of two-component systems and can minimize adhesive
waste by eliminating the need to purge during start up, shut down, and
line-down scenarios.
Floor space
Light-curable material assembly processes have a smaller
footprint since racking, batch process ovens, and cooling racks are
unnecessary. The light-curable material assembly process offers compatibility
with JIT manufacturing or Kanban production lines. Floor space savings enables
the opportunity to expand the production operation and increases the value of
dollars of product produced per square foot of floor space.
Potential accumulated cost reductions in the aforementioned
opportunity areas are illustrated in Fig. 1 and can result in at least a 30
percent savings in overall process costs.
Light-curable materials offer numerous opportunities to
increase productivity and reduce waste in assembly operations. Instant
on-demand cure, automated in-line inspection, solvent-free formulations, and
the smaller footprint of the light-cure process are just some of the benefits
of LCMs that provide significant, positive impacts to the bottom line.
For more information, visit: www.dymax.com
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