If ozone-depleting substances had not been banned, by the year 2065 nearly two-thirds of the Earth’s ozone would have been depleted, the ultraviolet radiation would have risen 650 percent, and the harmful effects to wildlife and humans would have increased, according to a new computer simulation program developed by researchers.

Atmospheric chemists from NASA's Goddard Space Flight Center, Greenbelt, Md., Johns Hopkins University, Baltimore, and the Netherlands Environmental Assessment Agency, have developed the simulation to determine what “might have been” if chlorofluorocarbons (CFCs) and similar chemicals were not banned through the Montreal Protocol treaty. The simulation used a comprehensive model that included atmospheric chemical effects, wind changes, and radiation changes. The analysis has been published online in the journal Atmospheric Chemistry and Physics.

“Ozone science and monitoring has improved over the past two decades, and we have moved to a phase where we need to be accountable,” said Goddard scientist Paul Newman, who is co-chair of the United Nations Environment Programme’s Scientific Assessment Panel to review the state of the ozone layer and the environmental impact of ozone regulation. “We are at the point where we have to ask: Were we right about ozone? Did the Montreal Protocol work? What kind of world was avoided by phasing out ozone-depleting substances?”

Ozone is Earth’s natural sunscreen, absorbing and blocking most of the incoming UV radiation from the sun and protecting life from DNA-damaging radiation. The gas is naturally created and replenished by a photochemical reaction in the upper atmosphere where UV rays break oxygen molecules (O2) into individual atoms that then recombine into three-part molecules (O3). As it is moved around the globe by upper level winds, ozone is slowly depleted by naturally occurring atmospheric gases. It is a system in natural balance.

In the new analysis, the team started with the Goddard Earth Observing System Chemistry-Climate Model (GEOS-CCM), an earth system model of atmospheric circulation that accounts for variations in solar energy, atmospheric chemical reactions, temperature variations and winds, and other elements of global climate change. For instance, the new model accounts for how changes in the stratosphere influence changes in the troposphere (the air masses near Earth's surface). Ozone losses change the temperature in different parts of the atmosphere, and those changes promote or suppress chemical reactions.

The researchers then increased the emission of CFCs and similar compounds by 3 percent per year, a rate about half the growth rate for the early 1970s. Then they let the simulated world evolve from 1975 to 2065.

By the simulated year 2020, 17 percent of all ozone is depleted globally, as assessed by a drop in Dobson Units (DU), the unit of measurement used to quantify a given concentration of ozone. An ozone hole starts to form each year over the Arctic, which was once a place of prodigious ozone levels.

By 2040, global ozone concentrations fall below 220 DU, the same levels that currently comprise the "hole" over Antarctica. (In 1974, globally averaged ozone was 315 DU.) The UV index in mid-latitude cities reaches 15 around noon on a clear summer day (a UV index of 10 is considered extreme today.), giving a perceptible sunburn in about 10 minutes. Over Antarctica, the ozone hole becomes a year-round fixture.

In the 2050s, something strange happens in the modeled world: Ozone levels in the stratosphere over the tropics collapse to near zero in a process similar to the one that creates the Antarctic ozone hole.

By the end of the model run in 2065, global ozone drops to 110 DU, a 67 percent drop from the 1970s. Year-round polar values hover between 50 and 100 DU (down from 300-500 in 1960). The intensity of UV radiation at Earth's surface doubles; at certain shorter wavelengths, intensity rises by as much as 10,000 times. Skin cancer-causing radiation soars.

The real world of CFC regulation has been somewhat kinder. Production of ozone-depleting substances was mostly halted about 15 years ago, though their abundance is only beginning to decline because the chemicals can reside in the atmosphere for 50 to 100 years. The peak abundance of CFCs in the atmosphere occurred around 2000, and has decreased by roughly 4 percent to date.

Stratospheric ozone has been depleted by 5 to 6 percent at middle latitudes, but has somewhat rebounded in recent years. The largest recorded Antarctic ozone hole was recorded in 2006.